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Finite element simulation of electrochemically reversible‚ quasi−reversible and irreversible linear sweep voltammetry at the wall tube electrode

OV Klymenko‚ DJ Gavaghan‚ KE Harriman and RG Compton

Abstract

A finite element approach for numerical simulation of linear sweep voltammetry at the wall tube electrode is presented. Working curves and surfaces are computed and reported which permit the analysis of reversible, quasi-reversible and irreversible voltammograms for all voltage scan rates. (C) 2002 Elsevier Science B.V. All rights reserved

ISSN
00220728
Journal
Journal of Electroanalytical Chemistry
Keywords
kinetics
Number
1
Pages
25–31
Publisher
Elsevier Science
Volume
531
Year
2002